This post will be updated as announcements come out for start times for 10/7 from the twelve day selection process that most TV networks adhere to. Please understand that games can be held until next Sunday if a broadcaster wants to wait on the results of the Week Five games. Most conferences have the possibility of having all or part of their games held for a six day hold of the start time.
Here's what I guessed based on the available openings (they'll prove to be incorrect) and here is the current schedule for the week as several FBS games do have their time & television/webcast assignments already accounted for.
All times Eastern.
Pac-12 Six Day Holds (8pm FOX or 10:45pm ESPN)
Washington St. at Oregon
California at Washington
12pm FOX: Iowa St. at Oklahoma
12pm ABC/ESPN/ESPN2: Penn St. at Northwestern
12pm ABC/ESPN/ESPN2: Wake Forest at Clemson
12pm ESPN/ESPN2 or SEC: Ole Miss at Auburn
12pm ESPN/ESPN2 or SEC: Georgia at Vanderbilt
12pm FS1: Texas Tech at Kansas
12pm ESPNU: Temple at East Carolina
12pm BTN: Illinois at Iowa
12pm CBSSN: Eastern Michigan at Toledo
12:20pm ACC Network: Duke at Virginia
12:30pm ACC RSNs: Pittsburgh at Syracuse
2pm ESPN3: Central Michigan at Ohio
2pm ESPN3: Stephen F. Austin at Sam Houston St.
2:30pm ESPN3: Bowling Green at Miami (OH)
3pm ESPN3: UL-Monroe at Texas St.
3:30pm CBS: LSU at Florida
3:30pm ABC or ESPN: Miami (FL) at Florida St.
3:30pm ABC or ESPN: Notre Dame at North Carolina
3:30pm ESPN2: Minnesota at Purdue
3:30pm FS1: West Virginia at TCU
3:30pm BTN: Charleston Southern at Indiana
3:30pm ESPN3: Western Michigan at Buffalo
3:30pm ESPN3: Ball St. at Akron
3:30pm ESPN3: Kent St. at Northern Illinois
3:30pm ESPN3: New Mexico St. at Appalachian St.
4pm FOX: Maryland at Ohio St.
4pm ESPNU: Tulsa at Tulane
4pm SEC: Arkansas at South Carolina
4pm Pac-12: Oregon St. at USC
5pm ESPN3: UL-Lafayette at Idaho
5pm Southland Digital: Incarnate Word at Southeastern Louisiana
6:30pm ESPN3: Georgia St. at Coastal Carolina
7pm FS1: Kansas St. at Texas
7pm CBSSN: SMU at Houston
7pm FOX Sports Southwest+: Central Arkansas at Houston Baptist
7:15pm ESPN: Alabama at Texas A&M
7:15pm ESPN2: Virginia Tech at Boston College
7:30pm ABC: Michigan St. at Michigan
7:30pm SEC: Missouri at Kentucky
8pm Pac-12: Arizona at Colorado
8pm ESPNU: UCF at Cincinnati
8pm BTN: Wisconsin at Nebraska
8pm Eleven Sports: McNeese at Abilene Christian
10:15pm FS1: Stanford at Utah
10:45pm ESPN2: San Diego St. at UNLV